I'm on the road and don't have immediate access to a Win10 machine so this info's from searching on the web.
Editing the PATH variable to add your nand2tetris\tools directory:
o Use search (hourglass lower left on desktop if you don't already have "search the web and windows" visible) and type in "environment".
o Select "Edit the system environment variables"
o Hit "Environment Variables" button
o Find "PATH" (case insensitive) in the System variables list; you may need to scroll the list.
o Select it, hit Edit... button, and add the full path to your nand2tetris\tools directory to the end of the path.
You can see an example of this in this video about setting the PATH variable for Java
https://www.youtube.com/watch?v=l1VxWWubxFoIf you are starting from zero with the command prompt, here's how to open it in Windows 10
https://www.youtube.com/watch?v=VyiGZW0fTxk--Mark